key term - [Fe(CN)6]³⁻

Definition

[Fe(CN)6]³⁻, known as the ferricyanide ion, is a complex ion consisting of a central iron (Fe) atom coordinated to six cyanide (CN) ligands. This ion is an example of a coordination compound, where the arrangement of the ligands around the metal center influences its chemical properties and reactivity. The charge of -3 indicates that this ion has three more electrons than protons, making it an anion.

5 Must Know Facts For Your Next Test

1. [Fe(CN)6]³⁻ has an oxidation state of +3 for the iron atom, which is important for understanding its electronic configuration and reactivity.
2. The geometry of [Fe(CN)6]³⁻ is octahedral due to the arrangement of six cyanide ligands around the central iron ion.
3. Cyanide is a strong field ligand, leading to significant splitting of the d-orbitals in the iron center, which affects its color and magnetic properties.
4. [Fe(CN)6]³⁻ can participate in various redox reactions, especially with its reduced form, [Fe(CN)6]⁴⁻, known as ferrocyanide.
5. This complex is often used in electrochemical applications and as an indicator in various chemical analyses due to its stability and unique properties.

Review Questions

• How does the arrangement of ligands in [Fe(CN)6]³⁻ affect its geometric structure and properties?
  • In [Fe(CN)6]³⁻, the presence of six cyanide ligands surrounding the iron center creates an octahedral geometry. This specific arrangement influences the electronic distribution within the metal center, leading to d-orbital splitting. As a result, the properties such as color and magnetic behavior are determined by how these ligands interact with the iron atom.
• Discuss the significance of oxidation states in understanding the behavior of [Fe(CN)6]³⁻ during redox reactions.
  • [Fe(CN)6]³⁻ has an oxidation state of +3 for iron, making it susceptible to reduction to [Fe(CN)6]⁴⁻. Understanding oxidation states is crucial in redox chemistry because they indicate how electrons are transferred between species. In reactions involving ferricyanide and ferrocyanide, this change in oxidation state highlights its role in electron transfer processes and its applications in electrochemistry.
• Evaluate the role of [Fe(CN)6]³⁻ in coordination chemistry and its impact on practical applications.
  • [Fe(CN)6]³⁻ serves as a key example in coordination chemistry due to its stable structure and well-defined properties. Its use in electrochemical applications demonstrates how coordination compounds can facilitate electron transfer. The complex's stability makes it valuable as a standard in analytical chemistry and various industrial processes, impacting fields ranging from environmental monitoring to materials science.

Related terms

Coordination Compound: A compound formed by the coordination of a metal atom or ion with ligands, which can be neutral molecules or anions.

Ligand: An atom, ion, or molecule that donates a pair of electrons to a central metal atom or ion in a coordination complex.

Oxidation State:

The charge of an atom in a compound, which indicates its degree of oxidation or reduction relative to its elemental state.